(Cobaltoceniumylamido)pyridinium hexafluoridophosphate
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چکیده
منابع مشابه
5-Azido-4-dimethylamino-1-methyl-1,2,4-triazolium Hexafluoridophosphate and Derivatives
5-Azido-4-(dimethylamino)-1-methyl-1,2,4-triazolium hexafluoridophosphate was synthesized from the corresponding 5-bromo compound with NaN3. Reaction with bicyclo[2.2.1]hept-2-ene yielded a tricyclic aziridine, addition of an N-heterocyclic carbene resulted in a triazatrimethine cyanine, and reduction with triphenylphosphane gave the 5-amino derivative. The crystal structures of three nitrogen-...
متن کاملμ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]chromium(III)} bis(hexafluoridophosphate)
The title compound, [Cr(2)Cl(2)O(C(18)H(18)N(4))(2)](PF(6))(2), is isostructural with the V(III) analogue. Each Cr(III) atom is chelated by the tetra-dentate tris-(2-pyridylmeth-yl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octa-hedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridgin...
متن کامل(Acetonitrile-κN)[2-(diphenylphosphanyl)ethanamine-κ2 N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
In the title cationic Cp(*)Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η(5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl-phosphino)ethyl-amine ligand and an additional acetonitrile mol-ecule in a piano-chair conformation. The PF(6) (-) anion is disordered over two sets of sites with occupancies of 0.779 (7) an...
متن کاملphenyl]phenol}iron(II) hexafluorido- phosphate
In the complex salt [ -1-chloro-2-(pyrrolidin-1-yl)benzene]( -cyclopentadienyl)iron(II) hexafluoridophosphate, [Fe(C5H5)(C10H12ClN)]PF6, (I), the complexed cyclopentadienyl and benzene rings are almost parallel, with a dihedral angle between their planes of 2.3 (3) . In a related complex salt, ( -cyclopentadienyl){2-[ -2-(pyrrolidin-1-yl)phenyl]phenol}iron(II) hexafluoridophosphate, [Fe(C5H5)(C...
متن کاملCrystal structure of bis(1,3-dimethoxyimidazolin-2-ylidene)silver(I) hexafluoridophosphate, N-heterocyclic carbene (NHC) complex
The title salt, [Ag(C5H8N2O2)2]PF6, was obtained by deprotonation and metalation of 1,3-di-meth-oxy-imidazolium hexa-fluorido-phosphate using silver(I) oxide in methanol. The C-Ag-C angle in the cation is 178.1 (2)°, and the N-C-N angles are 101.1 (4) and 100.5 (4)°. The meth-oxy groups adopt an anti conformation. In the crystal, anions (A) are sandwiched between cations (C) in a layered arrang...
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ژورنال
عنوان ژورنال: IUCrData
سال: 2021
ISSN: 2414-3146
DOI: 10.1107/s2414314621004600